Halogen bond induced phosphorescence of capped γ-amino acid in the solid state.
نویسندگان
چکیده
The Boc and N,N'-dicyclohexylurea capped γ-amino acid upon monobromination showed phosphorescence in the solid state. The compound exhibited different photoluminescence intensity and lifetimes in crystals obtained from ethyl acetate and methanol. X-ray crystallography revealed that the intermolecular C=O…Br halogen bond directs the heavy atom effect to produce the phosphorescence.
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عنوان ژورنال:
- Chemical communications
دوره 49 79 شماره
صفحات -
تاریخ انتشار 2013